Evolution of <sup>231</sup> Pa and <sup>230</sup> Th in overflow waters of the North Atlantic
Bibliographic record
Abstract
Abstract. Many paleoceanographic studies have sought to use the 231Pa / 230Th ratio as a proxy for deep ocean circulation rates in the North Atlantic. As yet, however, no study has fully assessed the concentration of, or controls on, 230Th and 231Pa in waters immediately following ventilation at the start of Atlantic meridional overturning. To that end, full water-column 231Pa and 230Th concentrations were measured along the GEOVIDE section, sampling a range of young North Atlantic deep waters. Th-230 and 231Pa concentrations in the water column are lower than those observed further south in the Atlantic, ranging between 0.004 and 0.738 dpm/1000l, and between 0.023 and 0.295 dpm/1000l, respectively. Both 230Th and 231Pa profiles generally increase with water depth from surface to deep water, followed by decrease near the seafloor, with this feature most pronounced in the Labrador Sea (LA Sea) and Irminger Sea (IR Sea). Analyzing this dataset with Extended Optimum Multi-Parameter (eOMP) Analysis and CFC-based water mass age indicates that the low values of 230Th and 231Pa in water near the seafloor of the LA Sea and IR Sea are related to the young waters present in those regions. This importance of water age is confirmed for 230Th by a strong correlation between 230Th and water mass age (though this relationship is less clear, for 231Pa and 231Pa / 230Th ratio). Scavenged 231Pa and 230Th were estimated and compared to their Potential Total concentrations in the water column. The result shows that more 230Th is scavenged (~ 80 %) relative to 231Pa (~ 40 %), consistent with the relatively higher particle-reactivity of 230Th. Enhanced scavenging for both nuclides is demonstrated near the seafloor in young overflow waters. Calculation of meridional transport of 230Th and 231Pa with this new GEOVIDE dataset enables a complete budget for 230Th and 231Pa for the North Atlantic. Results suggest that net transport southward of 230Th and 231Pa across GEOVIDE is smaller than transport further south in the Atlantic, and indicates that the flux to sediment in the North Atlantic is equivalent to 96 % of the production of 230Th, and 77 % of the production for 231Pa. This result confirms a significantly higher advective loss of 231Pa to the south relative to 230Th and supports the use of 231Pa / 230Th to assess meridional transport at a basin scale.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".