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Record W4254234415 · doi:10.1002/047084289x.rn01274

Allyl Acetate

2011· reference-entry· en· W4254234415 on OpenAlexaff
Étienne Bélanger, Jean‐François Paquin

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2011
Typereference-entry
Languageen
FieldChemistry
TopicAnalytical Chemistry and Chromatography
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsChemistryAcetic acidAlkeneOxidizing agentAllyl bromideAmmonium acetateOrganic chemistryButyl acetateSolubilityAqueous solutionNuclear chemistrySolventCatalysis

Abstract

fetched live from OpenAlex

[591-87-7] C5H8O2 (MW 100.12) InChI = 1S/C5H8O2/c1-3-4-7-5(2)6/h3H,1,4H2,2H3 InChIKey = FWZUNOYOVVKUNF-UHFFFAOYSA-N (alkene with significant reactivity; susceptible to allylation and cross-coupling reactions) Alternate Name: acetic acid 2-propenyl ester or 3-acetoxy-1-propene. Physical Data: bp 104–105 °C; 0.928 g ml−1 Solubility: sol in most organic solvents. Form Supplied in: colorless liquid; widely available. Purification: removal of peroxides is achieved by treatment with crystalline ferrous ammonium sulfate followed by washing with aqueous solutions of 5% NaHCO3 and saturated CaCl2 and then drying over Na2SO3 and subsequent fractional distillation. Handling, Storage, and Precautions: allyl acetate is an irritant and can be toxic if inhaled or ingested. Allyl acetate is a cancer-suspect agent and should be used only in a well-ventilated fume hood. Toxicity (oral) rat LD50: 130 mg kg−1. Allyl acetate is flammable and is incompatible with strong oxidizing agents, bases, and peroxides. To prevent leakage, store in a cool place.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.067
Threshold uncertainty score0.223

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0670.042

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.236
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations0
Published2011
Admission routes1
Has abstractyes

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