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Record W4256169266 · doi:10.1515/iupac.64.0310

Conversion of Temperatures and Thermodynamic Properties to the Basis of the International Temperature Scale of 1990

2016· dataset· en· W4256169266 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueIUPAC Standards Online · 2016
Typedataset
Languageen
FieldEngineering
TopicAdvanced Power Generation Technologies
Canadian institutionsRoyal Military College of Canada
Fundersnot available
KeywordsThermodynamicsEnthalpyThermodynamic temperatureScale of temperatureHeat capacityWork (physics)Basis (linear algebra)Scale (ratio)Entropy (arrow of time)International Temperature Scale of 1990ChemistryStatistical physicsMathematicsPhysicsMathematical analysisGeometry

Abstract

fetched live from OpenAlex

Tables of temperature differences between the International Temperature Scale of 1990 (ITS-90) and earlier temperature scales (IPTS-68, EPT-76, IPTS-48, and ITS-27) are presented. These tables also contain values of the derivatives of these differences with respect to temperature. Analytical equations to reproduce the temperature difference (T90 – T68) and its first derivative are also given. This information is needed for the adjustment of thermodynamic results to the basis of the ITS-90. Thus, for the most accurate thermodynamic results, it is preferable to change the temperatures of the original work to the ITS-90 and then recalculate the thermodynamic results on this basis. However, conversion formulae based upon a Taylor expansion of the enthalpy have been derived previously by Douglas (J. Res. Natl. Bur. Stand., Sect. A 73, 451–470 (1969)). These equations are greatly simplified when the differences between the two temperature scales are small. Approximate effects resulting from the conversion from the IPTS-68 to the ITS-90 and from the IPTS-48 to the ITS-90 for existing calorimetric determinations of heat capacity, enthalpy, and entropy have been calculated with the equations of Douglas for ND4ReO4(s), BaSnF4(s), α-Al2O3(s), BeO·Al2O3(s), BeO·3Al2O3(s), and Mo(s). The results of these calculations are given in tables which can be used to assess conveniently the approximate effects on thermodynamic properties due to the differences in these temperature scales. It is found that only the most accurate thermodynamic results require examination and possible adjustment because of a change in the temperature scale.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Dataset · Consensus signal: none
Teacher disagreement score0.525
Threshold uncertainty score0.390

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.280
Teacher spread0.275 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it