Dissolved Organic Matter at the Fluvial-Marine Transition in the Laptev Sea Using in situ Data and Ocean Color Remote Sensing
Bibliographic record
Abstract
Abstract. River water is the main source of dissolved organic carbon (DOC) in the Arctic Ocean. DOC plays an important role in the Arctic carbon cycle and its export from land to sea is expected to increase as ongoing climate change accelerates permafrost thaw. However, transport pathways and transformation of DOC in the land-to-ocean transition are mostly unknown. We collected DOC and aCDOM(λ) samples from 11 expeditions to river, coastal and offshore waters and present a new DOC-aCDOM(λ) model for the fluvial-marine transition zone in the Laptev Sea The aCDOM(λ) characteristics revealed that the DOM in samples of this dataset are primarily of terrigenous origin. Observed changes in aCDOM and its spectral slopes indicate that DOM is modified by microbial- and photo-degradation. Ocean Color Remote Sensing (OCRS) provides the absorption coefficient of colored dissolved organic matter (aCDOM(λ)sat) at λ = 440 or 443 nm, which can be used to estimate DOC concentration at high temporal and spatial resolution over large regions. We tested the statistical performance of five OCRS algorithms and evaluated the plausibility of the spatial distribution of derived aCDOM(λ)sat. The ONNS algorithm showed the best performance compared to in situ aCDOM(440) (r2 = 0.72). Additionally, we found ONNS-derived aCDOM(440), in contrast to other algorithms, to be partly independent of sediment concentration, making ONNS the most suitable aCDOM(λ)sat algorithm for the Laptev Sea region. The DOC-aCDOM(λ) model was applied to ONNS-derived aCDOM(440) and retrieved DOC concentration maps showed moderate agreement to in situ data (r2 = 0.53). The in situ and satellite-retrieved data were offset by up to several days, which may partly explain the weak correlation for this dynamic region. Satellite-derived surface water DOC concentration maps from MERIS satellite data demonstrate rapid removal of DOC within short time periods in coastal waters of the Laptev Sea, which is likely caused by physical mixing and different types of degradation processes. Using samples from all occurring water types leads to a more robust DOC-aCDOM(λ) model for the retrievals of DOC in Arctic shelf and river waters.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.001 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.001 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".