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Record W4281396835 · doi:10.1021/acs.jpcc.2c03987

Persistent Photogenerated State Attained by Femtosecond Laser Irradiation of Thin <i>T</i><sub>d</sub>-MoTe<sub>2</sub>

2022· article· en· W4281396835 on OpenAlex
Meixin Cheng, Shazhou Zhong, Nicolás Rivas, T. Dekker, Ariel A. Petruk, Patrick Gicala, Kostyantyn Pichugin, Fangchu Chen, Xuan Luo, Yuping Sun, Adam W. Tsen, Germán Sciaini

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2022
Typearticle
Languageen
FieldMaterials Science
TopicPhase-change materials and chalcogenides
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaCanada Foundation for Innovation
KeywordsFemtosecondLaserMaterials sciencePhotoexcitationIrradiationPhononPhase transitionExcitationOpticsNanocrystalline materialOptoelectronicsCondensed matter physicsNanotechnologyPhysics

Abstract

fetched live from OpenAlex

Laser excitation has emerged as a means to expose hidden states of matter and promote phase transitions on demand. Such laser-induced transformations are often rendered possible owing to the delivery of spatially and/or temporally manipulated light, carrying energy quanta well above the thermal background. Here, we report time-resolved broadband femtosecond (fs) transient absorption measurements on thin flakes of the Weyl semimetal candidate Td-MoTe2 subjected to various levels and schemes of fs-photoexcitation. Our results reveal that impulsive fs-laser irradiation alters the interlayer behavior of the low temperature Td phase as evidenced by the persistent disappearance of its characteristic coherent 1A1 ≈ 13 cm–1 shear phonon mode. We found that this structural transformation is likely related to lattice strain formation, withstands thermal cycling, and can be reverted to the 1T′ phase by fs-laser treatment at room temperature. Since interlayer shear strain was encountered to lead to a topologically distinct phase in an analogous compound, our work opens the door to the reversible optical control of electronic properties in this class of materials.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.747

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.216
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it