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Record W4281656139 · doi:10.5194/amt-15-3439-2022

Ground-based validation of the MetOp-A and MetOp-B GOME-2 OClO measurements

2022· article· en· W4281656139 on OpenAlexafffund
Gaïa Pinardi, Michel Van Roozendaël, François Hendrick, Andreas Richter, Pieter Valks, Ramina Alwarda, Kristof Bognar, Udo Frieß, J. Granville, Myojeong Gu, P. V. Johnston, Cristina Prados‐Román, Richard Querel, Kimberly Strong, Thomas Wagner, F. Wittrock, Margarita Yela

Bibliographic record

VenueAtmospheric measurement techniques · 2022
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of Toronto
FundersEurostarsCanadian Space AgencyMax-Planck-Institut für ChemieSerono Symposia International FoundationEuropean Organization for the Exploitation of Meteorological SatellitesMinisterio de Ciencia e InnovaciónUniversity of LeedsEnvironment and Climate Change CanadaBelgian Federal Science Policy Office
KeywordsDifferential optical absorption spectroscopySatelliteEnvironmental scienceZenithRemote sensingAtmospheric sciencesMeteorologySCIAMACHYOzoneTroposphereAbsorption (acoustics)PhysicsGeography

Abstract

fetched live from OpenAlex

Abstract. This paper reports on ground-based validation of the atmospheric OClO data record produced within the framework of EUMETSAT's Satellite Application Facility on Atmospheric Chemistry Monitoring (AC SAF) using the Global Ozone Monitoring Experiment (GOME)-2A and GOME-2B instrument measurements, covering the 2007–2016 and 2013–2016 periods, respectively. OClO slant column densities are compared to correlative measurements collected from nine Zenith-Scattered-Light Differential Optical Absorption Spectroscopy (ZSL-DOAS) instruments from the Network for the Detection of Atmospheric Composition Change (NDACC) distributed in both the Arctic and Antarctic. Sensitivity tests are performed on the ground-based data to estimate the impact of the different OClO DOAS analysis settings. On this basis, we infer systematic uncertainties of about 25 % (i.e., about 3.75×1013 molec. cm−2) between the different ground-based data analyses, reaching total uncertainties ranging from about 26 % to 33 % for the different stations (i.e., around 4 to 5×1013 molec. cm−2). Time series at the different sites show good agreement between satellite and ground-based data for both the inter-annual variability and the overall OClO seasonal behavior. GOME-2A results are found to be noisier than those of GOME-2B, especially after 2011, probably due to instrumental degradation effects. Daily linear regression analysis for OClO-activated periods yield correlation coefficients of 0.8 for GOME-2A and 0.87 for GOME-2B, with slopes with respect to the ground-based data ensemble of 0.64 and 0.72, respectively. Satellite minus ground-based offsets are within 8×1013 molec. cm−2, with some differences between GOME-2A and GOME-2B depending on the station. Overall, considering all the stations, a median offset of about -2.2×1013 molec. cm−2 is found for both GOME-2 instruments.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.227
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.038
GPT teacher head0.224
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2022
Admission routes2
Has abstractyes

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