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Development of an Efficient System for Blue Energy Production Based on Reverse Electrodialysis (RED) by Optimizing Electrolyte Composition: Experimental and Theoretical Simulations

2022· article· en· W4281723131 on OpenAlex
Syed Abdullah Shah, Zeeshan Haider, Majid Shahbabaei, Daejoong Kim

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnergy & Fuels · 2022
Typearticle
Languageen
FieldEngineering
TopicMembrane-based Ion Separation Techniques
Canadian institutionsUniversity of Alberta
FundersNational Research Foundation of Korea
KeywordsElectrolyteReversed electrodialysisChemistryElectrodialysisMembraneDiffusionIon exchangeAdsorptionIonic radiusInorganic chemistryChemical engineeringAnalytical Chemistry (journal)IonChromatographyThermodynamicsPhysical chemistryElectrodeOrganic chemistry

Abstract

fetched live from OpenAlex

Herein, the effect of electrolyte composition (single vs salt mixture) on the performance of reverse electrodialysis (RED) has been investigated using lab-made sulfonated poly(ether ether ketone) (sPEEK) cation exchange membrane (CE) membrane and Neosepta, a commercially available anion exchange (AE) membrane. The efficiency of the RED cell was monitored by measuring open-circuit voltage (OCV), power density (PD), and gross power density (PDgross). The effect of feed solution flow and concentration was analyzed by using several electrolytes (LiCl, NaCl, KCl, and NH4Cl) and mixed composition (NaKCl and NaNH4Cl). NaCl solution among single electrolytes exhibited the highest performance with a PD of 1.77 Wm–2, which was improved further by intermixing with KCl and NH4Cl. For the case of binary mixtures, NaNH4Cl showed a PD of 2.51 Wm–2, which is 42% higher compared to that of NaCl possibly due to the inferior stack resistance. A molecular dynamics (MD) simulation was performed to further investigate the adsorption-diffusion properties of CEM and AEM at the molecular scale. A positive correlation was observed between MD simulation and experimental measurements regarding the competitive adsorption of cations into the sPEEK membrane with the following trend NH4+ > K+ > Na+ > Li+, which is associated with the ionic radius and hydration energies of respective cations.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.332
Threshold uncertainty score0.767

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.222
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it