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Record W4284967786 · doi:10.1039/d2sc01909d

Visible-light-induced cross-coupling of aryl iodides with hydrazones <i>via</i> an EDA-complex

2022· article· en· W4284967786 on OpenAlexafffund
Pan Pan, Shihan Liu, Yu Lan, Huiying Zeng, Chao‐Jun Li

Bibliographic record

VenueChemical Science · 2022
Typearticle
Languageen
FieldChemistry
TopicRadical Photochemical Reactions
Canadian institutionsMcGill UniversityCentre in Green Chemistry and Catalysis
FundersNatural Sciences and Engineering Research Council of CanadaHigher Education Discipline Innovation ProjectCanada Foundation for InnovationNational Natural Science Foundation of ChinaCanada Research ChairsFonds Québécois de la Recherche sur la Nature et les TechnologiesJoint Research CentreInternational Joint Research Center for Green Catalysis and Synthesis
KeywordsArylHydrazoneChemistryPhotosensitizerPhotochemistryTrifluoromethylReagentElectron transferVisible spectrumHalideAcceptorExcited stateMedicinal chemistryOrganic chemistryMaterials science

Abstract

fetched live from OpenAlex

Visible-light-induced catalyst-free cross-coupling of aryl iodides with hydrazones via single-electron-transfer was reported. The mechanistic investigations showed that the association of hydrazone anion with aryl iodides formed an EDA complex.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0010.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.294
Teacher spread0.270 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations38
Published2022
Admission routes2
Has abstractyes

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