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Record W4285192842 · doi:10.5267/j.ccl.2022.6.002

Use of the compound (2-(4-chlorophenyl)-3-hydroxy-4H-chromene-4-one) as a ligand complex formation by copper (II)

2022· article· en· W4285192842 on OpenAlexvenueno aff
Itnawita Itnawita, Ganis Fia Kartika, Sofia Anita, T. Abu Hanifah, G.A. Guntur, U. Shyfaa

Bibliographic record

VenueCurrent Chemistry Letters · 2022
Typearticle
Languageen
FieldChemistry
TopicSynthesis and biological activity
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryLigand (biochemistry)CopperChloroformAbsorption (acoustics)ChlorideMetalFlavonolsMedicinal chemistryBenzoyl chlorideNuclear chemistryStereochemistryOrganic chemistryFlavonoid

Abstract

fetched live from OpenAlex

Flavanol compounds are chalcone derivatives, generally found in hydroxy substituted forms that can act as ligands. Hydroxy-substituted flavonols are found in many plants but in very small amounts. In order to enrich and expand the use of this compound as a ligand, the synthetic methods were carried out through structural variations, one of which was by substitution using chloride and then the compound (2-(4-chlorophenyl)-3-hydroxy-4H-chromene-4-one) was obtained. In this research, the study was conducted using the compound (2-(4-chlorophenyl)-3-hydroxy-4H-chromene-4-one) as a ligand for complex formation with copper (II). From the results of the study, the mole ratio of the ligand with copper (II) metal was 2:1, pH 7.01 with a complex stability time of 15-25 minutes. The complex formed is bright yellow in color and soluble in chloroform. From the characterization of the resulted complex, it was appeared that Cu-flavonol chloride with UV-Vis spectrophotometer showed maximum absorption at wavelengths 273 and 429 indicating the presence of benzoyl and cinnamoyl peaks, with FT-IR showing the wave number 1545cm-1 indicating the presence of Cu=O-Cu bonds and absorption at 682 cm-1 indicating the presence of Cu-O bonds.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.062
GPT teacher head0.243
Teacher spread0.182 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2022
Admission routes1
Has abstractyes

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