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Record W4287447289 · doi:10.1021/acsenergylett.2c01417

Rechargeable Metal–Hydrogen Peroxide Battery, A Solution to Improve the Metal–Air Battery Performance

2022· article· en· W4287447289 on OpenAlexafffund
Samira Siahrostami

Bibliographic record

VenueACS Energy Letters · 2022
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsUniversity of Calgary
FundersCanada First Research Excellence Fund
KeywordsBattery (electricity)RedoxHydrogen peroxideBifunctionalChemistryOxygenMaterials scienceChemical engineeringCatalysisInorganic chemistryPower (physics)EngineeringOrganic chemistry

Abstract

Rechargeable metal–air batteries are set to play an important role in electrifying the transportation sector and transitioning to a sustainable energy society with zero carbon footprint. However, their performance is vastly hampered by the sluggish kinetics of oxygen redox reactions at the air electrode. Herein, a rechargeable metal–hydrogen peroxide battery is introduced that is air-free and uses onsite generated and reduced hydrogen peroxide (H2O2) as an oxygen source for charging and discharging. Replacing oxygen redox reactions with H2O2 redox reactions results in a much faster kinetics and a significant improvement in the overall battery performance. Using computationally driven material design with a set of thermodynamic rules, highly stable, active, and selective bifunctional catalyst materials for H2O2 generation and reduction are proposed. This technology has the potential to overcome the long-standing issues with metal–air batteries paving the path for advancing the next-generation rechargeable battery technology based on H2O2 redox chemistry.

Stored with the screening record, where it is evidence for the labels above.

How this classification was reachedexpand

The three-model screen

all 5,600 screened works →

All three models called this out of scope.

stratum: aff_core · design weight: 5595.24 (the sample is stratified; any rate computed without the weight is wrong)
Claude Opus 4.8OUT
genre: empirical
about Canada: no
confidence: high

Electrochemistry study of a rechargeable metal-hydrogen peroxide battery.

GPT-5.6 (high)OUT
genre: empirical
about Canada: no
confidence: high

The study develops a rechargeable battery technology rather than examining research.

Grok 4.5OUT
genre: empirical
about Canada: no
confidence: high

Battery electrochemistry proposal for metal–hydrogen peroxide systems; domain energy materials.

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.000

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.191
Teacher spread0.183 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations26
Published2022
Admission routes2
Has abstractyes

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