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Record W4289344830 · doi:10.1073/pnas.2203937119

Carbon mineralization with concurrent critical metal recovery from olivine

2022· article· en· W4289344830 on OpenAlex
Fei Wang, David Dreisinger

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueProceedings of the National Academy of Sciences · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicCO2 Sequestration and Geologic Interactions
Canadian institutionsUniversity of British Columbia
FundersMitacs
KeywordsOlivineMineralization (soil science)Carbon fibersMetalGeochemistryGeologyMaterials scienceMetallurgySoil science

Abstract

fetched live from OpenAlex

Carbon dioxide utilization for enhanced metal recovery (EMR) during mineralization has been recently developed as part of CCUS (carbon capture, utilization, and storage). This paper describes fundamental studies on integrating CO 2 mineralization and concurrent selective metal extraction from natural olivine. Nearly 90% of nickel and cobalt extraction and mineral carbonation efficiency are achieved in a highly selective, single-step process. Direct aqueous mineral carbonation releases Ni 2+ and Co 2+ into aqueous solution for subsequent recovery, while Mg 2+ and Fe 2+ simultaneously convert to stable mineral carbonates for permanent CO 2 storage. This integrated process can be completed in neutral aqueous solution. Introduction of a metal-complexing ligand during mineral carbonation aids the highly selective extraction of Ni and Co over Fe and Mg. The ligand must have higher stability for Ni-/Co- complex ions compared with the Fe(II)-/Mg- complex ions and divalent metal carbonates. This single-step process with a suitable metal-complexing ligand is robust and utilizes carbonation processes under various kinetic regimes. This fundamental study provides a framework for further development and successful application of direct aqueous mineral carbonation with concurrent EMR. The enhanced metal extraction and CO 2 mineralization process may have implications for the clean energy transition, CO 2 storage and utilization, and development of new critical metal resources.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.570
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.034
GPT teacher head0.297
Teacher spread0.263 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it