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Record W4289917556 · doi:10.17816/humeco106218

Application inductively coupled plasma mass spectrometry for assessing the content of essential and toxic elements in whole blood of unexposed adults in the Russian Federation

2022· article· en· W4289917556 on OpenAlexaboutno aff
Н.В. Зайцева, Т.С. Уланова, A.V. Nedoshitova, G.A. Veikhman, M. V. Volkova, Е.В. Стенно

Bibliographic record

VenueEkologiya Cheloveka (Human Ecology) · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicHeavy Metal Exposure and Toxicity
Canadian institutionsnot available
Fundersnot available
KeywordsInductively coupled plasma mass spectrometryRussian federationMass spectrometryEnvironmental chemistryChemistryInductively coupled plasmaRadiochemistryAnalytical Chemistry (journal)ChromatographyPlasmaPhysicsNuclear physicsGeography

Abstract

fetched live from OpenAlex

BACKGROUND: Determination of the essential and toxic elements in human blood is an important and urgent task in monitoring, environmental, and hygienic studies accomplished in evidence-based medicine when the population health risks are assessed.
 AIM: Biomonitoring of unexposed adult population in the Russian Federation, interpretation of the obtained data taking into account international requirements.
 MATERIAL AND METHODS: The contents of V, Cr, Mn, Ni, Cu, Zn, As, Se, Sr, Cd, Tl and Pb were determined in the blood of adults (n=80, aged 45.83.7 years) living in rural areas in the Western Urals region of the Russian Federation and in the territory of the North of Eastern Siberia (n=90, age 38.27.6 years). The measurements were carried out using Agilent 7500cx quadrupole inductively coupled plasma mass spectrometer (Agilent Technologies, USA) with an octopole reaction-collision cell (ORS) in conformity with the Methodical guidelines 4.1.3230-14 and 4.1.3161-14 (FR.1.31.2014.17064) developed by the authors. We compared the range of P5P95 values for unexposed groups of the adult population of the Western Urals and the North of Eastern Siberia with data from hygiene studies in Germany, Italy, France, and Canada.
 RESULTS: The arithmetic mean content of elements in blood of adults Western Urals region amounted to 0.13 g/l (V); 4.75 g/l (Cr); 13.41 g/l (Mn); 4.06 g/l (Ni); 827 g/l (Cu); 5369 g/l (Zn); 0.42 g/l (As); 123 g/l (Se); 22.75 g/l (Sr); 0.45 g/l (Cd); 0.04 g/l (Tl); 14.37 g/l (Pb). The validity of the results was confirmed by analyzing standard samples of SERONORMTM Whole Blood L1 and SERONORMTM Whole Blood L2 (Norway). The results are presented as basic statistical indicators: minimum and maximum values, arithmetic mean, 5th, 50th, 95th percentiles and are interpreted in accordance with up-to-date international requirements.
 CONCLUSION: We compared the range of P5P95 values for unexposed groups of adults in the Western Urals and the North of Eastern Siberia region with the results produced by several hygienic studies conducted in Germany, Italy, France and Canada. As a result, we established elevated concentrations of chromium, manganese, and nickel in the blood of adults from Russia. The contents of copper, zinc, selenium, and arsenic in the blood of adults living in the Russian Federation were different from the reference values used in such diagnostic laboratories as ALS Scandinavia, SIVR List Italy and in the monograph by Norbert Titz (USA).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.657
Threshold uncertainty score0.351

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.262
Teacher spread0.244 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

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