Anisotropic magnetic property of single crystals <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mi>R</mml:mi><mml:msub><mml:mrow><mml:mi mathvariant="normal">V</mml:mi></mml:mrow><mml:mn>6</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mi>Sn</mml:mi></mml:mrow><mml:mn>6</mml:mn></mml:msub></mml:math> <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">Y</mml:mi><mml:mo>,</mml:mo><mml:mo> </mml:mo><mml:mi>Gd</mml:mi><mml:mtext>−</mml:mtext><mml:mi>Tm</mml:mi><mml:mo>,</mml:mo><mml:mo> </mml:mo><mml:mi>Lu</mml:mi><mml:mo>)</mml:mo></mml:math>
Bibliographic record
Abstract
${R\mathrm{V}}_{6}{\mathrm{Sn}}_{6}$ $(R=\mathrm{Y}, \mathrm{Gd}\text{\ensuremath{-}}\mathrm{Tm}, \mathrm{Lu})$ single crystals are synthesized by the Sn-flux method and their physical properties are characterized by magnetization, resistivity, and specific heat measurements. Powder x-ray diffraction patterns of all samples can be well indexed with the hexagonal ${\mathrm{HfFe}}_{6}{\mathrm{Ge}}_{6}$-type structure, where rare-earth atoms form hexagonal layers and vanadium atoms form kagome layers. At high temperatures, magnetic susceptibility measurements of moment-bearing rare-earth ions $(R=\mathrm{Gd}\text{\ensuremath{-}}\mathrm{Tm})$ follow Curie-Weiss behavior. Effective moments estimated from the polycrystalline average of magnetic susceptibility curves are consistent with the values for free ${R}^{3+}$ ions. Strong magnetic anisotropy due to crystalline electric field effects is observed for moment-bearing rare-earth ions, except ${\mathrm{GdV}}_{6}{\mathrm{Sn}}_{6}$. The easy magnetization direction is determined to be the $c$ axis for $R=\mathrm{Tb}\text{\ensuremath{-}}\mathrm{Ho}$ and $ab$ plane for $R=\mathrm{Er}$ and Tm. The vanadium ions in ${R\mathrm{V}}_{6}{\mathrm{Sn}}_{6}$ possess no magnetic moment. The compounds for $R=\mathrm{Y}$ and Lu exhibit typical characteristics of paramagnetic metals. At low temperatures, the magnetic ordering is confirmed from magnetization, specific heat, and resistivity: the highest ${T}_{N}=4.9$ K for ${\mathrm{GdV}}_{6}{\mathrm{Sn}}_{6}$ and the lowest ${T}_{N}=2.3$ K for ${\mathrm{HoV}}_{6}{\mathrm{Sn}}_{6}$. No magnetic ordering is observed down to 1.8 K for $R=\mathrm{Er}$ and Tm. A slight deviation of the magnetic ordering temperature from the de Gennes scaling suggests the dominant Ruderman-Kittel-Kasuya-Yosida exchange interaction between rare-earth moments in metallic ${R\mathrm{V}}_{6}{\mathrm{Sn}}_{6}$ compounds.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.007 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".