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Record W4292648648 · doi:10.1139/cjc-2021-0282

Enhanced solar light photocatalytic and antimicrobial activity of green noble metal/TiO<sub>2</sub> nanorods

2022· article· en· W4292648648 on OpenAlex
Hanan H. Mohamed, Tamer E. Youssef

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueCanadian Journal of Chemistry · 2022
Typearticle
Languageen
FieldEnergy
TopicTiO2 Photocatalysis and Solar Cells
Canadian institutionsnot available
Fundersnot available
KeywordsPhotocatalysisNanorodNoble metalNanocompositeNanomaterialsSurface plasmon resonanceVisible spectrumNanoparticleChemistryNanotechnologyChemical engineeringMaterials scienceNuclear chemistryMetalCatalysisOrganic chemistryOptoelectronics

Abstract

fetched live from OpenAlex

Au/TiO 2 and Pt/TiO 2 nanocomposites have been processed using a green method. Au and Pt colloidal nanoparticles have been primarily synthesized by mixing their corresponding metal ions with an aqueous solution of corn husk extract, followed by anchoring on the as-synthesized TiO 2 nanorods. The structural and morphological properties of green-prepared nanomaterials were systematically investigated by various techniques. The UV–VIS absorption measurements confirmed the formation of colloidal Au and Pt with λ max at 550 and 345 nm, respectively. TEM results show anchoring of spherical Au particles (40 nm) on TiO 2 nanorods while smaller Pt particles have been observed on Pt/TiO 2 composite. It has been shown that the highest visible light harvesting capability was earned for Au/TiO 2 composite due to the surface plasmon resonance (SPR) of Au nanoparticles. The photocatalytic and antimicrobial activity of the nanomaterials was investigated for disinfection of Escherichia coli under solar light irradiation. The green synthesized nanocomposites showed enhanced solar light photocatalytic and antimicrobial activity. The best photocatalytic and antimicrobial activity was obtained for Au/TiO 2 . This evidences the enhanced SPR of Au nanoparticles and hence an enhancement in the solar light accessible by TiO 2 so that a higher amount of reactive oxygen species can be generated, which enhances photocatalytic and antibacterial activity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.852

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.183
Teacher spread0.177 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it