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Record W4292648648 · doi:10.1139/cjc-2021-0282

Enhanced solar light photocatalytic and antimicrobial activity of green noble metal/TiO<sub>2</sub> nanorods

2022· article· en· W4292648648 on OpenAlexvenueno aff
Hanan H. Mohamed, Tamer E. Youssef

Bibliographic record

VenueCanadian Journal of Chemistry · 2022
Typearticle
Languageen
FieldEnergy
TopicTiO2 Photocatalysis and Solar Cells
Canadian institutionsnot available
Fundersnot available
KeywordsPhotocatalysisNanorodNoble metalNanocompositeNanomaterialsSurface plasmon resonanceVisible spectrumNanoparticleChemistryNanotechnologyChemical engineeringMaterials scienceNuclear chemistryMetalCatalysisOrganic chemistryOptoelectronics

Abstract

fetched live from OpenAlex

Au/TiO2 and Pt/TiO2 nanocomposites have been processed using a green method. Au and Pt colloidal nanoparticles have been primarily synthesized by mixing their corresponding metal ions with an aqueous solution of corn husk extract, followed by anchoring on the as-synthesized TiO2 nanorods. The structural and morphological properties of green-prepared nanomaterials were systematically investigated by various techniques. The UV–VIS absorption measurements confirmed the formation of colloidal Au and Pt with λmax at 550 and 345 nm, respectively. TEM results show anchoring of spherical Au particles (40 nm) on TiO2 nanorods while smaller Pt particles have been observed on Pt/TiO2 composite. It has been shown that the highest visible light harvesting capability was earned for Au/TiO2 composite due to the surface plasmon resonance (SPR) of Au nanoparticles. The photocatalytic and antimicrobial activity of the nanomaterials was investigated for disinfection of Escherichia coli under solar light irradiation. The green synthesized nanocomposites showed enhanced solar light photocatalytic and antimicrobial activity. The best photocatalytic and antimicrobial activity was obtained for Au/TiO2. This evidences the enhanced SPR of Au nanoparticles and hence an enhancement in the solar light accessible by TiO2 so that a higher amount of reactive oxygen species can be generated, which enhances photocatalytic and antibacterial activity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.183
Teacher spread0.177 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2022
Admission routes1
Has abstractyes

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Same venueCanadian Journal of ChemistrySame topicTiO2 Photocatalysis and Solar CellsFrench-language works237,207