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Record W4293171354 · doi:10.1002/cjce.24617

Selective leaching of lithium ions from <scp>LiFePO<sub>4</sub></scp> powders using hydrochloric acid and sodium hypochlorite system

2022· article· en· W4293171354 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2022
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsnot available
FundersNatural Science Foundation of Beijing MunicipalityNational Natural Science Foundation of China
KeywordsLeaching (pedology)Hydrochloric acidLithium iron phosphateX-ray photoelectron spectroscopySodium carbonateInorganic chemistrySelective leachingMaterials scienceIron phosphateScanning electron microscopeChemistryPhosphateNuclear chemistrySodiumChemical engineeringMetallurgyElectrochemistrySulfuric acidOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract High‐efficiency and selective leaching of lithium ions from spent lithium iron phosphate (LiFePO 4 ) batteries is currently an urgent problem to be solved. Hydrochloric acid and sodium hypochlorite were used as acidic media and oxidant for recycling LiFePO 4 powders based on the stoichiometric ratio. The effect of operation conditions on leaching performance was investigated. The leaching yield of Li and Fe were higher than 95% and lower than 0.1% within 20 min at 15°C. In addition, X‐ray diffraction, X‐ray photoelectron spectroscopy, scanning electron microscopy, and laser particle size analysis characterizations were applied for revealing the selective leaching mechanism, the results of which indicated that the crystal structure of powders remained basically unchanged during the leaching process. Finally, an efficient and cost‐effective recycling process for LiFePO 4 powders was proposed, and lithium carbonate products with purity higher than 99.7% were obtained. The proposed recycling process shows strong industrial application potential for LiFePO 4 powders.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.089
Threshold uncertainty score0.654

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.184
Teacher spread0.175 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it