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Record W4296193538 · doi:10.1007/s10967-022-08446-3

Collaborative Study for Certification of Trace Elements in Uranium Ore Concentrate CRMs UCLO-1, UCHI-1, and UPER-1

2022· article· en· W4296193538 on OpenAlexafffundabout
Kelly L. LeBlanc, Kenny Nadeau, Juris Meija, Lu Yang, Paola A. Babay, Marta A. Bavio, Carrie Boome, Don Chipley, Roxana S. Cristaldo Leguizamón, Joanna S. Denton, Dana L. Drew, Mauricio Fernández, V. Fugaru, Victoria D. Genetti, F. García de Blas González, Jeremy Inglis, Slobodan V. Jovanović, Elizabeth Keegan, Tara Kell, Yoshiki Kimura, William S. Kinman, Stephen Kiser, Rachel Lindvall, E. Loi, Klaus Mayer, Jean‐François Mercier, Robert P. Millar, Adrian Nicholl, L. V. Orlovskaya, José Luis Ramella, A. T. Serban, Michael A. Sharp, Youqing Shi, Csaba Tóbi, Lautaro Valenzuela, Zsolt Varga, Anna Vesterlund, Marian Vîrgolici, Hitoshi Yamazaki, Erica Zubillaga, Ali El‐Jaby, Zoltán Mester

Bibliographic record

VenueJournal of Radioanalytical and Nuclear Chemistry · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicRadioactive contamination and transfer
Canadian institutionsSaskatchewan Research Council (Canada)Canadian Nuclear LaboratoriesCanadian Nuclear Safety CommissionQueen's UniversityHealth CanadaNational Research Council Canada
FundersLos Alamos National LaboratoryNational Research Council CanadaLawrence Livermore National LaboratoryU.S. Department of Energy
KeywordsUraniumCertified reference materialsCertificationInductively coupled plasma mass spectrometryMatrix (chemical analysis)TRACE (psycholinguistics)ChemistryMass spectrometryMaterials scienceMetallurgyChromatographyDetection limitPolitical science

Abstract

fetched live from OpenAlex

Abstract Trace impurity patterns are important nuclear forensic signatures in uranium ore concentrates (UOCs) and Certified Reference Materials (CRMs) are used to validate the analysis methods employed by end users. Herein, we discuss the certification campaign for three new UOC CRMs from the National Research Council Canada: UCLO-1 ( https://doi.org/10.4224/crm.2020.uclo-1 ), UCHI-1 ( https://doi.org/10.4224/crm.2020.uchi-1 ), and UPER-1 ( https://doi.org/10.4224/crm.2020.uper-1 ). This study involved 15 laboratories from 10 countries, using sector-field and (triple) quadrupole inductively-coupled plasma mass spectrometry to analyze 64 trace element impurities. We discuss the importance of the acids used for sample digestion, difficulties analyzing in a high uranium matrix, and data combination and uncertainty evaluation for this large dataset.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.525
Threshold uncertainty score0.944

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.233
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2022
Admission routes3
Has abstractyes

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