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Record W4296756220 · doi:10.5194/amt-15-5367-2022

The Microfluidic Ice Nuclei Counter Zürich (MINCZ): a platform for homogeneous and heterogeneous ice nucleation

2022· article· en· W4296756220 on OpenAlexfundno aff
Florin N. Isenrich, Nadia Shardt, Michael Rösch, Julia Nette, Stavros Stavrakis, Claudia Marcolli, Zamin A. Kanji, Andrew J. deMello, Ulrike Lohmann

Bibliographic record

VenueAtmospheric measurement techniques · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric aerosols and clouds
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaEidgenössische Technische Hochschule Zürich
KeywordsIce nucleusNucleationSupercoolingMashingIce crystalsMicrofluidicsMaterials scienceHomogeneousPolydimethylsiloxaneChemical physicsAtmosphere (unit)Chemical engineeringAmorphous iceNanotechnologyChemistryThermodynamicsMeteorologyOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

Ice nucleation in the atmosphere is the precursor to important processes that determine cloud properties and lifetime. Computational models that are used to predict weather and project future climate changes require parameterizations of both homogeneous nucleation (i.e. in pure water) and heterogeneous nucleation (i.e. catalysed by ice-nucleating particles, INPs). Microfluidic systems have gained momentum as a tool for obtaining such parameterizations and gaining insight into the stochastic and deterministic contributions to ice nucleation. To overcome the shortcomings of polydimethylsiloxane (PDMS) microfluidic devices with regard to temperature uncertainty and droplet instability due to continuous water adsorption by PDMS, we have developed a new instrument: the Microfluidic Ice Nuclei Counter Zürich (MINCZ). In MINCZ, droplets with a diameter of 75 µm are generated using a PDMS chip, and hundreds of these droplets are then stored in fluoropolymer tubing that is relatively impermeable to water and solvents. Droplets within the tubing are cooled in an ethanol bath. We validate MINCZ by measuring the homogeneous freezing temperatures of water droplets and the heterogeneous freezing temperatures of aqueous suspensions containing microcline, a common and effective INP in the atmosphere. We obtain results with a high accuracy of 0.2 K in measured droplet temperature. Pure water droplets with a diameter of 75 µm freeze at a median temperature of 237.3 K with a standard deviation of 0.1 K. Additionally, we perform several freeze–thaw cycles. In the future, MINCZ will be used to investigate the freezing behaviour of INPs, motivated by a need for better-constrained parameterizations of ice nucleation in weather and climate models, wherein the presence or absence of ice influences cloud optical properties and precipitation formation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.003
Threshold uncertainty score0.010

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.000
Science and technology studies0.0010.001
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.216
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations17
Published2022
Admission routes1
Has abstractyes

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