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Record W4300384618 · doi:10.48550/arxiv.1306.3423

Capillary leveling of stepped films with inhomogeneous molecular\n mobility

2013· preprint· en· W4300384618 on OpenAlexfundno aff
Joshua D. McGraw, Thomas Salez, Oliver Bäumchen, Élie Raphaël, Kari Dalnoki‐Veress

Bibliographic record

VenuearXiv (Cornell University) · 2013
Typepreprint
Languageen
FieldChemical Engineering
TopicRheology and Fluid Dynamics Studies
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of CanadaÉcole Supérieure de Physique et de Chimie Industrielles de la Ville de ParisDeutsche ForschungsgemeinschaftÉcole Normale Supérieure
KeywordsLaplace pressureCapillary actionViscosityMaterials scienceSurface tensionPolymerRheologyStackingThin filmMechanicsComposite materialThermodynamicsNanotechnologyPhysicsNuclear magnetic resonance

Abstract

fetched live from OpenAlex

A homogeneous thin polymer film with a stepped height profile levels due to\nthe presence of Laplace pressure gradients. Here we report on studies of\npolymeric samples with precisely controlled, spatially inhomogeneous molecular\nweight distributions. The viscosity of a polymer melt strongly depends on the\nchain length distribution; thus, we learn about thin-film hydrodynamics with\nviscosity gradients. These gradients are achieved by stacking two films with\ndifferent molecular weights atop one another. After a sufficient time these\nsamples can be well described as having one dimensional viscosity gradients in\nthe plane of the film, with a uniform viscosity normal to the film. We develop\na hydrodynamic model that accurately predicts the shape of the experimentally\nobserved self-similar profiles. The model allows for the extraction of a\ncapillary velocity, the ratio of the surface tension and the viscosity, in the\nsystem. The results are in excellent agreement with capillary velocity\nmeasurements of uniform mono- and bi-disperse stepped films and are consistent\nwith bulk polymer rheology.\n

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.164
Teacher spread0.134 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2013
Admission routes1
Has abstractyes

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