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Record W4307464921 · doi:10.1021/acs.jchemed.2c00548

A Problem-Based Approach to Teaching the Internal Standard Method by ATR-FTIR Spectroscopy

2022· article· en· W4307464921 on OpenAlex
Shannon L. W. Accettone, Cassandra DeFrancesco, Lori Van Belle, Joel D. Smith, Erin Giroux

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Chemical Education · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicChemistry and Chemical Engineering
Canadian institutionsTrent University
Fundersnot available
KeywordsQuality assuranceCalibrationInternal standardFourier transform infrared spectroscopyContext (archaeology)Quality (philosophy)Computer scienceChemistryAnalytical Chemistry (journal)EngineeringMathematicsMass spectrometryChromatographyPhysicsChemical engineeringStatisticsExternal quality assessment

Abstract

fetched live from OpenAlex

The ability of students to perform quantitative analysis is a fundamental aspect of analytical chemistry courses and laboratories. In this laboratory experiment, students quantitatively analyze both liquid and solid samples through the use of internal standard calibration and ATR-FTIR spectroscopy. Using a problem-based approach to selecting their internal standards, students gain a deeper understanding of the internal standard method of calibration and the process of selecting appropriate standards for the analysis of sodium benzoate and acetophenone. This experiment allows students to explore the internal standard method of calibration under a wider context of quality control and quality assurance as they frame their quantitative analyses through both internal and external quality assurance testing methods. In a survey of students undertaking this experiment, most students responded that the experiment provided them with a better understanding of the internal standard method of calibration, and the selection of internal standards, and offered them an opportunity to gain hands-on experience with ATR-FTIR spectroscopy.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.036
Threshold uncertainty score0.509

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.255
Teacher spread0.251 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it