Synthesis and characterization of new Co(II), Rh(III), and Pt(II) guanidine and thiourea complexes
Bibliographic record
Abstract
Guanidine- and thiourea-based complexes have been the subject of extensive study due to their wide range of potential applications, including but not limited to anti-cancer drugs, ion transporters, and sensors. Building upon previous work done in this group, we aimed to demonstrate a new series of organometallic complexes based on functionally diverse guanidine and thiourea ligands. Herein, the synthesis and characterization of new platinum, rhodium, and cobalt complexes is presented. While most of these complexes conformed to properties and behaviours in line with previous work, one complex based on a Pt(II) and guanidine derivative exhibited unusual supramolecular properties, demonstrating a larger self-assembled dimer consisting of six Pt(II) cations.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".