Physical, structural, thermal, and mechanical features combined with neutron and gamma radiation attenuation qualities of Sm2O3 doped transparent borate-rich glasses
Why this work is in the frame
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Bibliographic record
Abstract
Current work presents the synthesis of B2O3–Gd2O3–Li2O–Na2O–LiF‒Sm2O3 glass system via melt-quench approach and scrutiny of its mechanical, thermal, structural, physical, and nuclear radiation attenuation aspects. Raman scattering and Fourier transform infrared spectra revealed B–O stretching modes of BO4 groups linked to BO3 units with nonbridging oxygen atoms and BO3 and BO4 units' existence in the glass structure. By differential scanning calorimetry, glass transition and crystallization temperatures are identified. Relevant analysis showed all glasses' good thermal stability where glass transition temperature varied at 372–407 °C range. ΣR (fast neutron removal cross-section) and for energy 0.025 eV neutrons σT (total cross-section) are computed. In all glasses, 49.25 B2O3–10Gd2O3–10Li2O–10Na2O–20LiF-0.75Sm2O3 (mol%) sample holds higher ΣR (= 0.10207 cm−1). 48B2O3–10Gd2O3–10Li2O–10Na2O–20LiF–2Sm2O3 (mol%) glass possesses greater σT (= 736.675 cm−1) for thermal neutrons, hinting at added Sm2O3's favorable influence as Sm owns a better ability for neutron absorption than B. By Phy-X/PSD, μ/ρ (mass attenuation coefficient) is obtained at photon energy extent 15 keV‒15 MeV. Sm2O3 inclusion from 0 to 2 mol% minorly enhanced the μ/ρ values. Buildup factors estimated via geometric progression fitting method at 1–40 mean free path and energy 0.015–15 MeV span are maximal at medium energy region owing to Compton scattering process. 48B2O3–10Gd2O3–10Li2O–10Na2O–20LiF–2Sm2O3 (mol%) sample shows superior γ-ray blocking capacity in all glasses, suggesting Sm2O3's positive effect. Elastic moduli and Poisson's ratio are computed theoretically by bond compression and Makishima–Mackenzie models. It is identified that all glasses could tolerate longitudinal stress over shear stress.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it