Investigation of the equilibrium constant of <scp>NO</scp> absorption into diethylenetriaminecobalt( <scp>II</scp> ) solution
Bibliographic record
Abstract
Abstract Diethylenetriaminecobalt(II), [Co(DETA) 2 ] 2+ , formed by diethylenetriamine (DETA) coordinating with Co(II) ion, can be used to remove NO from flue gas. Diethylenetriaminecobalt(II) is capable of binding NO to form metal nitroso complexes. The determination of the equilibrium constant of the reaction between [Co(DETA) 2 ] 2+ and NO is important to the development of the technology for the elimination of NO from exhausted gas streams with diethylenetriaminecobalt solution. In this paper, the equilibrium constants of this reaction have been determined by a series of experiments in a bubble reactor at the range of 30–70°C under atmospheric pressure in the [Co(DETA) 2 ] 2+ solution of pH 7.5. All experimental data are in good agreement with the following equation: , where the changes in enthalpy and entropy are Δ H 0 = −38.89 kJ ⋅ mol −1 and Δ S 0 = −109.7 J ⋅ K −1 ⋅ mol −1 , respectively.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.002 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".