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Record W4312903451 · doi:10.56530/lcgc.na.ib7278q3

A Full Scan Data Review Tool to Match the Speed of Acoustic Ejection Mass Spectrometry

2022· article· en· W4312903451 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueLCGC North America · 2022
Typearticle
Languageen
FieldChemistry
TopicMass Spectrometry Techniques and Applications
Canadian institutionsSciex (Canada)
Fundersnot available
KeywordsMass spectrometryComputer scienceThroughputSample (material)Matching (statistics)Data extractionData qualityData miningChemistryEngineeringMathematicsChromatographyTelecommunications

Abstract

fetched live from OpenAlex

Acoustic ejection mass spectrometry (AEMS) has recently emerged as the premier ultrahigh-throughput mass spectrometric methodology for drug discovery and related fields. The ultrahigh analytical speed (~1 s/sample) of AEMS has significantly enhanced the efficiency of many high throughput applications. As a result, a data processing and reviewing tool with a matching speed is in high demand for the large amount of data generated, especially for applications such as quality control (QC) of compound collections and high throughput chemistry, where full-scan MS data required convoluted subsequent peak extraction and evaluation. In this study, we demonstrated the feasibility of a tool developed specifically for this purpose. The process using the tool involved automated splitting of the full scan data to correlate well positions with each signal peak, extraction of expected mass traces, and subsequent peak integration. Data evaluation based on verification rules, such as detected mass accuracy, isotopic pattern, and signal-to-noise ratio (S/N), enabled a comprehensive assessment of sample quality that was complemented by visualization in the form of a plate heat map generated from the selected rules. The tool demonstrated fast and straightforward data review and reporting and, more importantly, at a matching speed of sample analysis by acoustic ejection mass spectrometry. The choice of data processing and storage over the cloud further facilitated results sharing among data users.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.623
Threshold uncertainty score0.984

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.002
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0170.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.276
Teacher spread0.258 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it