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Record W4313051793 · doi:10.1039/d2ce01311h

Experimental and computational studies on pseudotetrahedral nickel(<scp>ii</scp>)-(<i>S</i> or <i>R</i>)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal

2022· article· en· W4313051793 on OpenAlex
Arezoo Saadati, Hadi Amiri Rudbari, Mahnaz Aryaeifar, Olivier Blacque, Isabel Correia, Mohammad Khairul Islam, Dennis Woschko, Takin Haj Hassani Sohi, Christoph Janiak, Mohammed Enamullah

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueCrystEngComm · 2022
Typearticle
Languageen
FieldMedicine
TopicMetal complexes synthesis and properties
Canadian institutionsnot available
FundersUniversity of IsfahanHeinrich-Heine-Universität DüsseldorfYork UniversityAlexander von Humboldt-Stiftung
KeywordsNickelChirality (physics)ChemistryMetalStereochemistryPhysicsQuantum mechanicsOrganic chemistry

Abstract

fetched live from OpenAlex

Synthesis of pseudotetrahedral bis[( S or R )-N-1-(phenyl)ethyl-(2,4-dihalogen-salicylaldiminato-κ 2 N,O)]-Δ/Λ-nickel( ii ), Δ/Λ-Ni( S or R )L 1–3 with Δ- or Λ-chirality induction at-metal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.199
Threshold uncertainty score0.925

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.098
GPT teacher head0.313
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it