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Record W4313149469 · doi:10.46427/gold2022.12407

Measuring CO<sub>2</sub> Exchange over the Hydromagnesite-Magnesite Playas in Atlin, B.C.

2022· article· en· W4313149469 on OpenAlexaff
Anne Martine Doucet, Frances Jones, Bethany Ladd, Andrew Black, Gregory M. Dipple, K. Ulrich Mayer

Bibliographic record

VenueGoldschmidt2022 abstracts · 2022
Typearticle
Languageen
FieldEnvironmental Science
TopicCO2 Sequestration and Geologic Interactions
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsMagnesiteGeologyGeochemistryEnvironmental scienceChemistryMagnesium

Abstract

fetched live from OpenAlex

The hydromagnesite-magnesite playas in Atlin, BC, are an important site for demonstrating carbonate mineral stability at the Earth's surface [1]. The playas represent a natural analogue for carbon capture and storage via ex-situ carbon mineralization. Additionally, Power et al. (2014) suggested that the playas degas CO 2 during carbonate mineral precipitation from the Mg-HCO 3 rich groundwater. The complex interactions between minerals, fluids and the atmosphere make Atlin an ideal site to test methods for measuring CO 2 fluxes in a predominantly abiotic geologic setting. Eddy covariance (EC) and dynamic closed chamber (DCC) systems, combined with meteorological sensors, were co-located to directly quantify rates and characterize processes governing the CO 2 flux across the playa-atmosphere interface. Data were collected continuously over 27 days in August 2020 and 12 days in 2021. The results from the DCC method show distinct diurnal oscillation of CO 2 fluxes, with average daytime fluxes of +0.170.36 mol m -2 s -1 and nighttime fluxes of -0.240.32 mol m -2 s -1 (positive upward and negative downward). The near-zero flux measured via the DCC method indicates minimal net exchange of carbon across the playaatmosphere interface. These observations imply that DCCmeasured CO 2 fluxes are governed predominantly by changes in CO 2 solubility in alkaline porewater related to diurnal temperature fluctuations and variations in CO 2 concentrations in ambient air above the ground surface. However, the EC data show a continuous positive flux averaging +1.39 mol m -2 s -1 (2020) and +1.11 mol m -2 s -1 (2021). The net flux of CO 2 measured by EC is from a source undetected by the DCC (i.e. CO 2 imported laterally from surrounding forests or released through preferential pathways in the playa). The use of two flux measurement methods reveals the importance of the scale and location at which CO 2 flux processes occur at this site and the necessity of cross-validation between methods. These findings provide insights for the larger-scale application of these methods for monitoring and verification of ex-situ carbon mineralization at enhanced weathering sites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.699
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0170.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.229
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

Explore more

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