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Record W4313499811 · doi:10.1155/2022/5455101

Study on H <sub>2</sub> S Occurrence in Low Sulfur Coal Seams

2022· article· en· W4313499811 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAdsorption Science & Technology · 2022
Typearticle
Languageen
FieldEngineering
TopicCoal Properties and Utilization
Canadian institutionsNexen (Canada)
FundersNational Natural Science Foundation of China
KeywordsCoalSulfurChemistryAdsorptionCoal miningMoistureHydrogen sulfideSulfideFlue-gas desulfurizationEnvironmental chemistryMineralogyOrganic chemistry

Abstract

fetched live from OpenAlex

Coal samples from the Shanxi Shaping coal mine were selected to investigate the occurrence of H 2 S in low sulfur coal seams. The adsorption mechanism of coal to H 2 S was explored, and an occurrence equation for H 2 S in coal seams was fitted through adsorption experiment results. The results showed that under ambient temperature and pressure conditions, the H 2 S adsorbed by coal reached equilibrium within 24 h. The increase in H 2 S concentrations and the moisture content of coal samples resulted in an increase in the adsorption capacity of H 2 S. Chemical adsorption of H 2 S by the coal also occurred. The total sulfur content in the coal increased, and water promoted the conversion from H 2 S to sulfur in coal. After adsorption, most of the H 2 S remains in the coal structure in the form of inorganic sulfur, such as sulfur hydride, iron sulfide sulfur, and monomeric sulfur, and a small proportion of H 2 S is bonded in the structure of the coal in the form of organic sulfur such as thiophene, C-S-C, and C-SH. Therefore, the higher the total sulfur content in coal, the greater the occurrence of H 2 S. The total amount of H 2 S increased exponentially with the concentration of free H 2 S and the moisture content of coal at equilibrium. This meant that the total amount of H 2 S in the coal seam could be estimated by fitting an equation according to the concentration of free H 2 S and the moisture content of coal seams. The concentration of free H 2 S decreased linearly with the increase in moisture content of the coal, therefore, the concentration of H 2 S in space could be reduced by injecting water into coal seams.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.105
Threshold uncertainty score0.453

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.003
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.243
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it