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Record W4313528312 · doi:10.1021/acs.jpcc.2c06120

Ultrafast Dynamics of the Topological Semimetal GdSb<sub><i>x</i></sub>Te<sub>2–<i>x</i>–δ</sub> in the Presence and Absence of a Charge Density Wave

2023· article· en· W4313528312 on OpenAlexfundno aff
Robert J. Kirby, Angela Montanaro, Francesca Giusti, André Koch-Liston, Shiming Lei, Ioannis Petrides, Prineha Narang, Kenneth S. Burch, Daniele Fausti, Gregory D. Scholes, Leslie M. Schoop

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2023
Typearticle
Languageen
FieldPhysics and Astronomy
TopicTopological Materials and Phenomena
Canadian institutionsnot available
FundersAir Force Office of Scientific ResearchDivision of Materials ResearchEuropean CommissionCanadian Institute for Advanced ResearchPrinceton Center for Complex MaterialsPrinceton UniversityGordon and Betty Moore FoundationU.S. Department of EnergyNational Science Foundation
KeywordsCharge density waveUltrashort pulseInfraredExcitationMaterials scienceMolecular physicsChemistryCondensed matter physicsChemical physicsPhysicsOptics

Abstract

fetched live from OpenAlex

Time-resolved dynamics in charge-density-wave materials have revealed interesting out-of-equilibrium electronic responses. However, these are typically only performed in a single material possessing a CDW. As such, it is challenging to separate subtle effects originating from the CDW. Here, we report on the ultrafast dynamics of the GdSb x Te 2– x –δ series of materials where E F can be tuned, resulting in a change from an undistorted tetraganal phase to a CDW with a wavevector that depends on x . Using mid-infrared, near-infrared, and visible excitation, we find the dynamics are sensitive to both E F and the presence of the CDW. Specifically, as the Sb content of the compounds increases, transient spectral features shift to higher probe energies. In addition, we observe an enhanced lifetime and change in the sign of the transient signal upon removing the CDW with high Sb concentrations. Finally, we reveal fluence- and temperature-dependent photoinduced responses of the differential reflectivity, which provide evidence of transient charge density wave suppression in related telluride materials. Taken together our results provide a blueprint for future ultrafast studies of CDW systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.028
Threshold uncertainty score0.380

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.220
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2023
Admission routes1
Has abstractyes

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