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Superconductivity in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>SrB</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">C</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math> clathrate

2023· article· lv· W4315705203 on OpenAlexaff
Li Zhu, Hanyu Liu, Maddury Somayazulu, Yue Meng, Piotr A. Guńka, Thomas B. Shiell, Curtis Kenney‐Benson, Stella Chariton, Vitali B. Prakapenka, Hyeok Yoon, Jarryd A. Horn, Johnpierre Paglione, Roald Hoffmann, R. E. Cohen, Timothy A. Strobel

Bibliographic record

VenuePhysical Review Research · 2023
Typearticle
Languagelv
FieldPhysics and Astronomy
TopicSuperconductivity in MgB2 and Alloys
Canadian institutionsCanadian Institute for Advanced Research
FundersArgonne National LaboratoryBasic Energy SciencesNational Nuclear Security AdministrationOffice of ScienceUniversity of MarylandNarodowa Agencja Wymiany AkademickiejCarnegie Institution of WashingtonGordon and Betty Moore FoundationU.S. Department of EnergyNational Science Foundation
KeywordsSuperconductivityMetastabilityPseudopotentialPhysicsCondensed matter physicsMaterials scienceCrystallographyChemistryQuantum mechanics

Abstract

fetched live from OpenAlex

We predict superconductivity for the carbon--boron clathrate ${\mathrm{SrB}}_{3}{\mathrm{C}}_{3}$ with ${T}_{c}=27\text{--}43\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ for Coulomb pseudopotential (${\text{\ensuremath{\mu}}}^{*}$) values between 0.17 and 0.10 using first-principles calculations with conventional electron--phonon coupling. Electrical transport measurements, facilitated by an in situ experimental design compatible with extreme synthesis conditions ($>3000\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ at 50 GPa), show nonhysteretic resistivity drops that track the calculated magnitude and pressure dependence of superconductivity for ${\text{\ensuremath{\mu}}}^{*}\ensuremath{\approx}0.15$, and transport measurements collected under applied magnetic fields indicate superconductivity with an onset ${T}_{c}$ of approximately 20 K at 40 GPa. Carbon-based clathrates thus represent a class of superconductors similar to other covalent metals like ${\mathrm{MgB}}_{2}$ and doped fullerenes. Carbon clathrates share structures similar to superconducting superhydrides with wide potential for tunable properties, and covalent C--B bonds allow metastable persistence at ambient conditions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.030

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0090.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.049
GPT teacher head0.312
Teacher spread0.262 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations57
Published2023
Admission routes1
Has abstractyes

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