Enhanced Blue Emission in Rb<sub>2</sub>HfCl<sub>6</sub> Double Perovskite via Bi<sup>3+</sup> Doping and Cs<sup>+</sup> Alloying
Bibliographic record
Abstract
Lead-free double perovskites offer non-toxic properties and strong emission via alloying and doping. Herein, we report the synthesis of Bi-doped pure Rb 2 HfCl 6 and Cs-alloyed RbCsHfCl 6 microcrystals. The pure Rb 2 HfCl 6 microcrystals are nearly non-emissive while alloying with Cs and Bi doping lead to strong deep blue emission at 466 nm with an increase in photoluminescence quantum yield from ∼0 to 66%. Density functional theory studies attest to the improved phase stability due to Cs-alloying and link photoluminescence to Bi 3+ dopant-induced localized states.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".