A Deeper Understanding of H<sub>2</sub> Evolution Entirely from Water via Diborane Hydrolysis
Bibliographic record
Abstract
Hydrogen (H 2 ) has drawn extensive attention due to its superior gravimetric capacity density and eco-friendly nature. Nowadays, hydrogen is mainly produced by the steam reforming of natural gas, a process that leads to massive emissions of greenhouse gases. Very recently, H 2 evolution upon hydrolysis of diboranes (e.g., B 2 (OH) 4 and B 2 pin 2 ) is promising because both H atoms of the released H 2 are obtained from water. This is different from the hydrolysis of sodium borohydride, dimethylaminoborane, ammonia borane, and tetramethyldisiloxane, where an H 2 is generated with only one H atom from H 2 O and the other one from hydrogen storage materials. Importantly, diborane hydrolysis in D 2 O could provide an easy and simple method for D 2 evolution. In this minireview, an overview of H 2 evolution upon diborane hydrolysis with an extraordinary emphasis on the recent developments in mechanism study and applications is presented. The future research emphasis and perspectives of H 2 evolution upon diborane hydrolysis have been suggested for commercialization as well.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.002 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.002 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".