Polyhedral oligomeric silsesquioxane‐based functional coatings: A review
Bibliographic record
Abstract
Abstract Polyhedral oligomeric silsesquioxane (POSS)‐based coatings have attracted significant attention from academia and industry over the past decades. The three‐dimensional nano‐sized cage with alternating SiO bonds forms the inorganic core of POSS molecules, while organic functional groups are covalently attached to the Si vertices. With this unique structure, they can be integrated with polymers via different approaches, including physical blending, covalent grafting, and chemical cross‐linking. And the inorganic/organic hybrid nature of POSS offers the coating materials with desirable mechanical, anti‐wetting, anti‐corrosive, icephobic, and fire‐retardant properties. This review focuses on the state‐of‐the‐art developments of POSS‐based functional coatings, while their challenges and future research directions are also discussed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".