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Record W4319920850 · doi:10.3390/membranes13020219

Pore-Scale Modeling of Microporous Layer for Proton Exchange Membrane Fuel Cell: Effective Transport Properties

2023· article· en· W4319920850 on OpenAlexaff
Heng Zhang, Xuanyu Shao, Zhigang Zhan, Mrittunjoy Sarker, Pang‐Chieh Sui, Po‐Ya Abel Chuang, Mu Pan

Bibliographic record

VenueMembranes · 2023
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsUniversity of Victoria
FundersBasic and Applied Basic Research Foundation of Guangdong ProvinceNational Natural Science Foundation of China
KeywordsProton exchange membrane fuel cellMicroporous materialMaterials scienceMicrostructureLattice Boltzmann methodsMembrane electrode assemblySaturation (graph theory)PorosityCapillary actionChemical engineeringComposite materialElectrodeChemistryFuel cellsThermodynamics

Abstract

fetched live from OpenAlex

A microporous layer (MPL) is a transition layer with a porous material structure, located between the gas diffusion layer (GDL) and catalyst layer (CL) in a proton exchange membrane fuel cell (PEMFC). It not only significantly improves electron transfer and heat conduction in membrane electrode assembly, but also effectively manages liquid water transport to enhance the fuel cell performance. The MPL is usually coated on one side of the GDL. The fragile nature of MPL makes it challenging to characterize the effective transport properties using experimental methods. In this study, a stochastic numerical method is implemented to reconstruct the three-dimensional microstructure of an MPL consisting of carbon particles and PTFE. The reliability of the MPL reconstructed model is validated using experimental data. The relationship between the effective transport properties and the compression strain is obtained using the Pore Scale Model (PSM), while the relationship between the liquid water saturation and capillary pressure is solved by Lattice Boltzmann Method (LBM). The effective transport properties in the MPL are then imported into the two-phase flow fuel cell model. It is found that the effective transport parameters in MPL obtained by PSM and LBM can improve the accuracy of the model calculation. This study provides an effective method to reconstruct the microstructure of MPL that can generate precise MPL transport parameters for utilization in various PEMFC performance prediction models.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.188
Threshold uncertainty score0.738

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.206
Teacher spread0.189 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2023
Admission routes1
Has abstractyes

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