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Record W4322001888 · doi:10.5194/egusphere-egu23-11571

Very short-lived halogens amplify recent and future ozone depletion trends in the tropical lower stratosphere.

2023· preprint· en· W4322001888 on OpenAlexaboutno aff
Julián Villamayor, Fernando Iglesias‐Suarez, Carlos A. Cuevas, Rafael P. Fernández, Qinyi Li, Marta Ábalos, Ryan Hossaini, Martyn P. Chipperfield, Douglas E. Kinnison, Simone Tilmes, Jean‐François Lamarque, Alfonso Saiz‐Lopez

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsnot available
Fundersnot available
KeywordsStratosphereMontreal ProtocolOzoneOzone depletionOzone layerAtmospheric sciencesClimatologyEnvironmental scienceMeteorologyGeographyPhysics

Abstract

fetched live from OpenAlex

Recent observational evidences show ongoing net ozone depletion in the tropical lower stratosphere (LS) since the late 20th century, in contrast to the overall stratospheric ozone recovery following controls in the Montreal Protocol to limit the production of long-lived ozone depleting substances. Such behavior is currently thought to be driven by dynamical transport accelerated by global warming. In contrast, the role of chemistry, i.e., the enhanced ozone depletion due to emissions of halogenated ozone-depleting very short-lived substances (VSLS) has been considered to be unimportant. Here we employ a chemistry-climate model with a comprehensive chemical scheme to demonstrate that VSLS chemistry accounts for around a quarter of the observed tropical LS negative ozone trend in 1998-2018. We attribute such an effect to chemical reactions with VSLS from natural and anthropogenic emissions in concert. Future projections show the persistence of the currently unaccounted for contribution of VSLS to ozone loss throughout the 21st century in the tropical LS, the only region of the global stratosphere not projecting an ozone recovery by 2100. Our results show evidence for the need of mitigation strategies for regulating anthropogenic VSLS emissions to preserve the present and future ozone layer in low latitudes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score0.028

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.044
GPT teacher head0.262
Teacher spread0.219 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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