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Record W4322211205 · doi:10.5194/egusphere-egu23-13875

Global emissions of five controlled CFCs have increased since 2

2023· preprint· en· W4322211205 on OpenAlexaboutno aff
Luke M. Western, Martin K. Vollmer, Paul B. Krummel, Karina E. Adcock, Paul E. Fraser, Christina M. Harth, R. L. Langenfelds, S. A. Montzka, Jens Mühle, Simon O’Doherty, D. E. Oram, Stefan Reimann, Matthew Rigby, Isaac Vimont, Ray F. Weiss, Dickon Young, Johannes C. Laube

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsnot available
Fundersnot available
KeywordsMontreal ProtocolGreenhouse gasEnvironmental scienceOzone layerOzoneOzone depletionProduction (economics)Consumption (sociology)Atmosphere (unit)Natural resource economicsEnvironmental protectionMeteorologyEconomicsGeographyEcology

Abstract

fetched live from OpenAlex

Production and consumption of ozone-depleting chlorofluorocarbons (CFCs) are controlled under the Montreal Protocol. CFC production for most applications was banned globally in 2010, albeit with exemptions for uses assumed to cause negligible emissions to the atmosphere, such as in the production of other chemicals. A few years ago, emissions of CFC-11 were reported to be increasing after their phase-out, most likely due to unreported production and non-compliance, which sparked widespread, renewed attention to this topic. Here we show that emissions of five other CFCs have increased since 2010, namely CFC-13, CFC-112a, CFC-113a, CFC-114a and CFC-115. Three of these CFCs are likely increasing due to their involvement in the production of non-ozone-depleting HFCs, which have largely replaced CFCs and HCFCs in many applications. The drivers behind the increase in the other two CFCs is unclear. While the impact of these CFCs on ozone layer recovery will likely be small, these long-lived CFCs are potent greenhouse gases and their CO2-equivalent emissions in 2020 were comparable to those of a mid-sized European country.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.099
Threshold uncertainty score0.198

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.001
Bibliometrics0.0010.002
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0000.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0080.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.256
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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