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Record W4322626725 · doi:10.1116/6.0002371

Hybrid octa-silane polyhedral oligomeric silsesquioxane (OS-POSS) optical films prepared by ion beam assisted evaporation

2023· article· en· W4322626725 on OpenAlexafffund
Artem Shelemin, O. Zabeida, Jincheng Qian, J.E. Klemberg-Sapieha, L. Martinů

Bibliographic record

VenueJournal of Vacuum Science & Technology A Vacuum Surfaces and Films · 2023
Typearticle
Languageen
FieldMaterials Science
TopicSilicone and Siloxane Chemistry
Canadian institutionsPolytechnique Montréal
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsSilsesquioxaneMaterials scienceSilaneEvaporationChemical vapor depositionCoatingIon beamSiliconDeposition (geology)Silicon oxideChemical engineeringRefractive indexAnalytical Chemistry (journal)IonComposite materialOptoelectronicsChemistryOrganic chemistryPolymerSilicon nitride

Abstract

fetched live from OpenAlex

Ion beam assisted thermal evaporation of the octa-silane polyhedral oligomeric silsesquioxane solid organic precursor was employed to deposit hybrid silicon oxide for the first time. This deposition process was primarily developed for ophthalmic lens applications as an alternative to the ion beam assisted chemical vapor deposition process. The main advantage of the proposed concept combining thermal evaporation and ion beam discharge is its transferability to industrial systems without significant scale-up investments. In the first part of this work, we performed a detailed diagnostic analysis (residual gas analysis and optical emission spectroscopy) of the effect of the experimental parameters on gas-phase processes. In the second part, we assessed and discussed the optical, chemical, structural, and mechanical properties of the deposited films. It has been found that the discharge current and oxygen gas ratio are the main parameters that adjust the coating properties and performance over a broad range. The adequately optimized combination of these two parameters allows one to fabricate flexible optical films with a low refractive index and a high elastic recovery.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.002
Science and technology studies0.0010.002
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.259
Teacher spread0.248 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2023
Admission routes2
Has abstractyes

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