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Distinct seasonality in vertical variations of tropospheric ozone over coastal regions of southern China

2023· article· en· W4322753328 on OpenAlexaff
Zhixiong Chen, Yangcheng Xie, Jane Liu, Lijuan Shen, Xugeng Cheng, Han Han, Mengmiao Yang, Yukun Shen, Tianliang Zhao, Jun Hu

Bibliographic record

VenueThe Science of The Total Environment · 2023
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric chemistry and aerosols
Canadian institutionsUniversity of Toronto
FundersNatural Environment Research CouncilMinistère de l'Education Nationale, de l'Enseignement Superieur et de la RechercheBundesministerium für Bildung und ForschungHarvard UniversityNational Natural Science Foundation of ChinaEuropean Commission
KeywordsSeasonalityChinaClimatologyTroposphereTropospheric ozoneEnvironmental scienceOzoneGeographyAtmospheric sciencesMeteorologyGeologyEcology

Abstract

fetched live from OpenAlex

The surface ozone pollution is strongly coupled with ozone variations above the ground. Using sufficient airborne ozone profiles during 2012-2018, this study reveals the tropospheric ozone distributions over four cities located in coastal regions of southern China. The 7-year mean tropospheric ozone profiles in the four cities consistently show a double-maxima profile, with a local maximum at 1 km altitude and the other in the middle-to-upper troposphere. Seasonally, springtime ozone is larger than the annual mean throughout the troposphere, while ozone in summer is high in the middle-to-upper troposphere, leading to largest vertical variations among seasons. Ozone in the middle-to-upper troposphere is lower in autumn than in spring and summer. The winter ozone is characterized with a minimum in the lower troposphere, and low values in the middle-to-upper troposphere, leading to least vertical variations among seasons. We untangle the causes for these complicated vertical ozone variations using the GEOS-Chem model. The tropospheric ozone over southern China is partitioned into locally produced ozone, regionally transported native ozone, imported ozone from outside of China (foreign ozone) and natural stratospheric ozone. The results suggest that the springtime ozone abundance is due to the enhanced import of foreign and stratospheric ozone and the intensified regional transport processes of native ozone. In summer, local ozone production is enhanced and regional transport of ozone in the middle-to-upper troposphere is strengthened due to upward air motions, while such transport becomes weaker in autumn leaving low ozone in the middle-to-upper troposphere. In winter, the intensive westerly jets promote foreign and stratospheric ozone again in the middle-to-upper troposphere, but the local ozone production and regional transport are sharply reduced, resulting in low ozone near the surface. This study provides new insights into regional ozone profiles and reveals the significance of vertical ozone variations on surface ozone prevention strategy.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.051
Threshold uncertainty score0.102

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.197
Teacher spread0.187 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations35
Published2023
Admission routes1
Has abstractyes

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