Corrosion and catalytic properties of electrodeposited nanocrystalline molybdenum
Bibliographic record
Abstract
Abstract Molybdenum (Mo) is a less toxic alternative to chromium for protective coatings. Mo possesses similar properties to Cr, although its electrochemical properties, particularly its passive behavior, have been less studied. We compare the passive behavior of electrodeposited Mo coatings to that of bulk metallic Mo in 3.5% sodium chloride (NaCl) solution. The results demonstrate a strong correlation between the microstructure and passive properties of the coating. Electrodeposited Mo has a higher tendency to passivate, a higher passive current density, and a larger passivation window compared to bulk Mo in 3.5% NaCl. The enhanced electrochemical behavior of the Mo coating is attributed to its nanometric structure and increased electrochemically active surface area. This study highlights the potential for the use of electrodeposited Mo as a safer and more environmentally friendly alternative to Cr coatings.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".