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Record W4324092507 · doi:10.5194/amt-2023-27

Controlled release testing of the static chamber methodology for direct measurements of methane emissions

2023· preprint· en· W4324092507 on OpenAlexafffund
James P. Williams, Khalil El Hachem, Mary Kang

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicCO2 Sequestration and Geologic Interactions
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of CanadaMcGill University
KeywordsMethaneVolume (thermodynamics)Environmental scienceGreenhouse gasMethane emissionsComponent (thermodynamics)Nuclear engineeringMethane gasProcess engineeringPetroleum engineeringChemistryPhysicsEngineeringThermodynamicsGeology

Abstract

fetched live from OpenAlex

Abstract. Direct measurements of methane emissions at the component level provide the level of detail necessary for developing actionable mitigation strategies. As such, there is a need to understand the magnitude of component level methane emission sources and test methane quantification methods that can capture methane emissions from component level sources. The static chamber method is a direct measurement technique that is being applied to measure large and complex methane sources such as oil and gas infrastructure. In this work we compile component level methane emission factors from the IPCC emission factor database to understand the magnitude of component level methane flowrates, review the tested flowrates and measurement techniques from 38 controlled release experiments, and perform 64 controlled release testing of static chambers methodology with mass flowrates of 1.02, 10.2, 102, and 512 grams of methane per hour (g/hour). We vary the leak properties, chamber shape, chamber size, and usage of fans to evaluate how these factors affect the accuracy of the static chamber method. We find that 99 % of component level methane emission rates from the IPCC emission factor database are below 100 g/hour, and that 76 % of previously-available controlled release experiments did not test for methane mass flowrates below 100 g/hour. We find that the static chamber method quantified methane flowrates with an overall accuracy of ±14 %, and that optimal chamber configurations (i.e., chamber shape, volume, usage of fans) can improve accuracy to below ±5 %. We find that smaller chambers (<20 L) performed better than larger volume chambers (>20 L), regardless of the shape of chamber or usage of fans. However, we found that the usage of fans can substantially increase the accuracy of larger chambers, especially at higher mass flowrates of methane (>100 g/hour). Overall, our findings can be used to engineer static chamber systems for future direct measurement campaigns targeting a wide range of sources, including landfills, manholes, and oil and natural gas infrastructure.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.008
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.424
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.008
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.342
GPT teacher head0.396
Teacher spread0.054 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2023
Admission routes2
Has abstractyes

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