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Record W4324380814 · doi:10.1080/01496395.2023.2189054

Purification of glycerol and its conversion to value-added chemicals: A review

2023· review· en· W4324380814 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueSeparation Science and Technology · 2023
Typereview
Languageen
FieldEngineering
TopicCatalysis for Biomass Conversion
Canadian institutionsUniversity of Saskatchewan
Fundersnot available
KeywordsGlycerolChemistryBiodiesel productionBiodieselPulp and paper industryValue addedOrganic chemistryChromatographyCatalysis

Abstract

fetched live from OpenAlex

An increase in demand for biodiesel production has resulted in increased production of glycerol, which is the main co-product of the process. Glycerol resulted from the biodiesel production is deemed as crude glycerol as it contains impurities such as free fatty acid, inorganic salts, water, and methanol. These impurities decrease economic value of glycerol, and for this reason, crude glycerol cannot be utilized as such. Hence, this low value product needs to be exploited via purification and value-addition for the benefit of biodiesel industry. In this review, the processes and different techniques employed for glycerol purification have been reviewed. Different methods of glycerol purification are compared for their suitability for various value-added chemicals from glycerol. There is no size one-fit all approach for glycerol purification, and the most promising method – membrane purification has not been optimized for industrial scale. In this review, conversion of purified glycerol into value-added chemicals such as 1,3-propanediol and glycerol carbonate via both catalytic and biochemical conversion processes have been explored. Furthermore, techno-economic aspect, which is crucial for industrial adaption of the process, has been discussed. Purified glycerol, when used for the production of value-added products, can be a promising income stream for biodiesel industry.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.970
Threshold uncertainty score0.621

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.004
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.040
GPT teacher head0.350
Teacher spread0.310 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it