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Record W4353086307 · doi:10.1029/2022gb007651

Memory and Management: Competing Controls on Long‐Term Nitrate Trajectories in U.S. Rivers

2023· article· en· W4353086307 on OpenAlexafffund
K. J. Van Meter, D. Byrnes, N. B. Basu

Bibliographic record

VenueGlobal Biogeochemical Cycles · 2023
Typearticle
Languageen
FieldEnvironmental Science
TopicSoil and Water Nutrient Dynamics
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaGlobal Water FuturesCanada First Research Excellence FundPennsylvania State University
KeywordsEnvironmental scienceEutrophicationWater qualityWatershedHydrology (agriculture)NitrateEcosystemNutrientDeposition (geology)EcologyStructural basin

Abstract

fetched live from OpenAlex

Abstract Excess nitrogen from intensive agricultural production, atmospheric N deposition, and urban point sources elevates stream nitrate concentrations, leading to problems of eutrophication and ecosystem degradation in coastal waters. A major emphasis of current US‐scale analysis of water quality is to better our understanding of the relationship between changes in anthropogenic N inputs within watersheds and subsequent changes in riverine N loads. While most water quality modeling assumes a positive linear correlation between watershed N inputs and riverine N, many efforts to reduce riverine N through improved nutrient management practices result in little or no short‐term improvements in water quality. Here, we use nitrate concentration and load data from 478 US watersheds, along with developed N input trajectories for these watersheds, to quantify time‐varying relationships between N inputs and riverine N export. Our results show substantial variations in watershed N import‐export relationships over time, with quantifiable hysteresis effects. Our results show that more population‐dense urban watersheds in the northeastern U.S. more frequently show clockwise hysteresis relationships between N imports and riverine N export, with accelerated improvements in water quality being achieved through the implementation of point‐source controls. In contrast, counterclockwise hysteresis dynamics are more common in agricultural watersheds, where time lags occur between the implementation of nutrient management practices and water‐quality improvements. Finally, we find higher tile‐drainage densities to be associated with more linear relationships between N inputs and riverine N. The empirical analysis in this study is bolstered by modeled simulations to reproduce and further explain drivers behind the hysteretic relationships commonly observed in the monitored watersheds.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.013
Threshold uncertainty score0.550

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.223
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2023
Admission routes2
Has abstractyes

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