Macro‐/mesoporous Metal–Organic Frameworks Templated by Amphiphilic Block Copolymers Enable Enhanced Uptake of Large Molecules
Bibliographic record
Abstract
Abstract The first synthesis of hierarchical porous metal–organic frameworks (HP‐MOFs) is reported through a solvent evaporation‐induced co‐assembly of polystyrene‐ block ‐poly(ethylene oxide) (PS‐ b ‐PEO) and MOF building blocks. The growth of MOFs is restricted to confined spaces formed by self‐assembled PS‐ b ‐PEO, and mesopores and/or macropores are created after removing PS‐ b ‐PEO by solvent rinsing. This approach avoids phase separation and competitive interactions between templates and MOF building blocks. Both amorphous and crystalline HP‐MOFs can be synthesized by finely controlling MOF growth conditions. Additionally, HP‐MOFs (ZIF‐L sheets) with honeycomb‐like channels show significantly enhanced incorporation of large guest molecules compared to microporous MOFs. This study establishes an efficient synthetic strategy for preparing HP‐MOFs with highly accessible mesopores and macropores for applications involving large molecules.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.001 | 0.000 |
| Insufficient payload (model declined to judge) | 0.022 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".