V<sub>2</sub>O<sub>3</sub>@C Microspheres as the High-Performance Cathode Materials for Advanced Aqueous Zinc-Ion Storage
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Bibliographic record
Abstract
Vanadium oxides attract increasing research interests for constructing the cathode of aqueous zinc-ion batteries (ZIBs) because of high theoretical capacity, but the low intrinsic conductivity and unstable phase changes during the charge/discharge process pose great challenges for their adoption. In this work, V 2 O 3 @C microspheres were developed to achieve enhanced conductivity and improved stability of phase changes. Compounding vanadium oxides and conductive carbon through the in-situ carbonization led to significant improvement of the cathode materials. ZIBs prepared with V 2 O 3 @C cathodes produce a specific capacity of 420 mA h g –1 at 0.2 A g –1 . A reversible capacity of 132 mA h g –1 was achieved at 21.0 A g –1 . After 2000 cycles, the electrode could still deliver a capacity of 202 mA h g –1 at the current of 5.0 A g –1 . Besides, the energy density of batteries constructed with the thus-prepared electrodes was about 294 W h kg –1 at 148 W kg –1 power. The in-situ compounding of V 2 O 3 and carbon resulted in a microstructure that facilitated the stable phase transformation of Zn x V 2 O 5– a · n H 2 O (ZnVOH), which provided more Zn 2+ storage activity than the original phase before electrochemical activation. Moreover, the in-situ compositing strategy presents a simple route to the development of ZIB cathodes with promising performance.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it