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Record W4376636314 · doi:10.1029/2022jd037749

Changes in Atmospheric Gaseous Elemental Mercury Concentrations and Isotopic Compositions at Mt. Changbai During 2015–2021 and Mt. Ailao During 2017–2021 in China

2023· article· en· W4376636314 on OpenAlexaff
Xian Wu, Xuewu Fu, Hui Zhang, Kaihui Tang, Xun Wang, Qianwen Deng, Leiming Zhang, Kaiyun Liu, Qingru Wu, Shuxiao Wang, Xinbin Feng

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2023
Typearticle
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsEnvironment and Climate Change Canada
FundersChinese Academy of SciencesNational Natural Science Foundation of China
KeywordsMercury (programming language)Environmental scienceChinaElemental mercuryEnvironmental chemistryChemistryGeography

Abstract

fetched live from OpenAlex

Abstract China is the largest contributor to the global total anthropogenic mercury (Hg) emissions. However, the trend in anthropogenic Hg emissions in recent years in China has not been effectively evaluated due to the lack of long‐term atmospheric Hg observations. This study documents the changes in atmospheric gaseous elemental mercury (GEM) concentrations and isotopic compositions at Mt. Changbai (MCB) in northeastern China during 2015–2021 and Mt. Ailao (MAL) in southwestern China during 2017–2021, and explores the potential factors controlling these changes. GEM concentrations showed continuous declines from 2015 to 2021 (−2.1 ± 0.6% yr−1) at MCB and from 2017 to 2021 (−4.0 ± 1.4% yr−1) at MAL. Accompanied with these GEM declines are positive shifts in δ202Hg (medians: from 0.42 to 0.46‰ at MCB and from 0.17 to 0.57‰ at MAL), and negative shifts in Δ199Hg (medians: from −0.17‰ to −0.21‰ at MCB and from −0.10‰ to −0.17‰ at MAL) and Δ200Hg values (medians: from −0.07‰ to −0.08‰ at MCB and from −0.03‰ to −0.05‰ at MAL) (at significant levels for Δ199Hg at MCB and δ202Hg and Δ199Hg at MAL). These changes were mainly caused by the decreases in regional anthropogenic emissions in the study areas. Based on a ternary mixing model with Δ199Hg and Δ200Hg as input, we estimate decline rates of 5.8 ± 2.8 and 4.8 ± 3.0% yr−1 for the regional anthropogenic GEM emissions in northeastern and southwestern China, respectively.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.121
Threshold uncertainty score0.240

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.322
Teacher spread0.298 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2023
Admission routes1
Has abstractyes

Explore more

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