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Record W4376867382 · doi:10.21203/rs.3.rs-2867671/v1

Cost-Effective Electrodeposited Mixed Transition Metal Electrocatalysts for Efficient Hydrogen Evolution Reaction

2023· preprint· en· W4376867382 on OpenAlexaff
Saeedeh Golrokhifar, Ali Shahroudi, Sajjad Habibzadeh

Bibliographic record

VenueResearch Square · 2023
Typepreprint
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsMcGill University
Fundersnot available
KeywordsElectrocatalystTafel equationTransition metalMaterials scienceTernary operationChemical engineeringManganeseNickelHydrogenInorganic chemistryCatalysisChemistryMetallurgyElectrodeElectrochemistryPhysical chemistryComputer scienceOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Hydrogen is a clean fuel with high energy density, considered one of the alternative energy sources of the future. Hydrogen evolution reaction (HER) could produce pure hydrogen on a large scale while striving for effective electrocatalysts. Here, binary and ternary mixed transition metals (Mn, Co, and Ni) were synthesized by an electrodeposition method and employed as efficient HER electrocatalysts. It was found that the combination of transition metals could positively tune the corresponding morphology and activity rather than using single metals. Namely, NiMn electrocatalysts with an onset potential of 83 mV and a Tafel slope of 103 mV.dec− 1 showed superior activity toward HER in alkaline media compared to the other developed electrocatalysts. This high activity was related to improved intrinsic activity, higher energy efficiency, and enhanced conductivity thanks to the synergy between manganese and nickel. NiMn electrocatalyst also displayed a durable and stable performance, rendering it a promising electrocatalyst for efficient electrocatalysis of HER.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.044
GPT teacher head0.344
Teacher spread0.300 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2023
Admission routes1
Has abstractyes

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