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Record W4376874658 · doi:10.1201/9781003027621-8

Nanomaterials under High-Pressure Conditions

2023· book-chapter· en· W4376874658 on OpenAlexaff
Denis Machon

Bibliographic record

Venuenot available
Typebook-chapter
Languageen
FieldEngineering
TopicLaser-Ablation Synthesis of Nanoparticles
Canadian institutionsInstitut interdisciplinaire d'innovation technologiqueUniversité de Sherbrooke
Fundersnot available
KeywordsNanomaterialsNanotechnologyMaterials science

Abstract

fetched live from OpenAlex

Two major effects of pressure in nanomaterials are discussed in this chapter. First, the pressure-induced phase transitions in nanomaterials often differ significantly from those of their bulk counterparts. This opens the opportunity of including surface energy contributions in thermodynamic models. The importance or even the dominance of surface atoms and the underlying surface state (point defects, ligands, etc.) greatly influence the thermodynamics and kinetics of phase transformations. This can lead to a competition between pressure-induced polymorphic transitions and amorphization depending on the defect density in the nanomaterials. Second, the mechanical properties of 2D materials such as graphene are difficult to apprehend because of their dimensionality. The variation over a wide range of pressure allows a better understanding of the stress transfer through the substrate and its role in the production of biaxial strain conditions. The mechanism of stress transmission to an atomically-thin material will be discussed, and a practical example that aims to determine the coupling between components in graphene-based nanocomposites will be presented.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.663
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0150.010

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.219
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designTheoretical or conceptual
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2023
Admission routes1
Has abstractyes

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