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Record W4377088681 · doi:10.1002/9781119780045.ch19

Molecular Gels–Barriers, Advances, and Opportunities

2023· other· en· W4377088681 on OpenAlexaff
Michael A. Rogers

Bibliographic record

Venuenot available
Typeother
Languageen
FieldMaterials Science
TopicSupramolecular Self-Assembly in Materials
Canadian institutionsUniversity of Guelph
Fundersnot available
KeywordsNanotechnologyStructuringChemistrySupersaturationBiochemical engineeringMaterials scienceOrganic chemistryEngineeringBusiness

Abstract

fetched live from OpenAlex

Molecular gels are predominantly liquid systems, which self-recognize and assemble via microscopic separation, nucleation and crystal growth resulting in a continuous self-assembled fibrillar network (SAFiNs). The aggregation of molecular gelators into SAFiNs requires a meticulous balance between contrasting parameters of solubility and those controlling epitaxial growth. Self-assembly is programmed with the position and type of functional group (molecular synthons) that coordinate non-covalent interactions. Unfortunately, the complex interplay between gelator structure and concentration, solvent chemistry, and supersaturation on self-assembly continues to impede the rational design of molecular gels, and researchers still rely on serendipitous discovery. As the food industry pushes to create zero waste, molecular refinement will produce a steady supply of precursor molecules ideally suited for biorefinery, which has already proven successful in designing new oil structuring compounds.Patience and persistence are required because research is still needed to fill in numerous fundamental knowledge gaps before these technologies can be applied to the food supply chain.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.011
Threshold uncertainty score0.038

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0030.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0010.003
Scholarly communication0.0040.009
Open science0.0010.003
Research integrity0.0020.003
Insufficient payload (model declined to judge)0.0110.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.261
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2023
Admission routes1
Has abstractyes

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