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Constraining the Capacity of Global Croplands to CO<sub>2</sub> Drawdown via Mineral Weathering

2023· review· en· W4379981082 on OpenAlexafffund
Fatima Haque, Reza Khalidy, Yi Wai Chiang, Rafael M. Santos

Bibliographic record

VenueACS Earth and Space Chemistry · 2023
Typereview
Languageen
FieldEnvironmental Science
TopicCO2 Sequestration and Geologic Interactions
Canadian institutionsUniversity of Guelph
FundersNatural Sciences and Engineering Research Council of CanadaOntario Agri-Food Innovation AllianceCanada First Research Excellence Fund
KeywordsWeatheringPedogenesisSoil production functionCarbonateSoil waterSoil scienceSilicateSilicate mineralsEarth scienceEnvironmental scienceGeologyEnvironmental chemistryGeochemistryChemistry

Abstract

fetched live from OpenAlex

Terrestrial enhanced weathering of alkaline silicate minerals is a promising climate change mitigation strategy with the potential to limit the global temperature rise. The formation and accumulation of pedogenic carbonate and bicarbonate in soils/subsoils and groundwater offers a large sink for C storage; the amount of soil inorganic carbon (SIC) presently held within soils has been estimated to be 720–950 Gt of C. These values can be augmented by the addition of a variety of calcium and magnesium silicates via enhanced weathering. While the concept of the application of finely milled silicate rocks for faster weathering rates is well established, there has been limited discussion on the role of local climate, natural SIC content (i.e., the SIC innately present in the soil), and soil pH (among other important agronomic factors) on silicate weathering when applied to croplands, especially in view that the aim is to establish terrestrial enhanced weathering as a carbon dioxide removal (CDR) strategy on a global scale. In this work, we emphasized the importance of soil pH and soil temperature on silicate weathering and looked to estimate an upper limit of (i.e., constrain) the global capacity until the year 2100 for enhanced rock weathering (ERW) to draw down CO 2 in the form of accumulated pedogenic carbonate or soluble bicarbonate. We assessed the global spatial distribution of cropland soil pH, which serves as a proxy for local innate SIC; annual rate of pluvial (rainfall) precipitation; and soil temperature, and found that the potential CO 2 drawdown difference between faster and slower weathering silicates is narrower in Asia, Africa, and South America, while the gap is larger for Europe, North America, and Oceania.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.974
Threshold uncertainty score0.612

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.278
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2023
Admission routes2
Has abstractyes

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