Front Cover: Piano‐Stool Ruthenium <i>N</i>‐Heterocyclic Carbene Complexes for <i>gem</i>‐Specific Catalytic Dimerization of Terminal Alkynes (Eur. J. Inorg. Chem. 21/2023)
Bibliographic record
Abstract
The Front Cover shows [RuClCp*(NHC)] complexes of varying wingtip groups playing a baseball game, the NHC Cup Final. The complex bearing the bulkiest NHC ligand is seen batting with a LiHMDS “base”-ball bat, illustrating the crucial role of the LiHMDS base in the catalytic reaction. The batter hits the incoming phenylacetylene pitch towards the outer field for a homerun, yielding the geminal-enyne product with 100 % selectivity, which is displayed on the score board. The complexes of less bulky NHC ligands are on the opposing team, as they are not able to selectively yield the geminal-enynes. The 25 °C temperature on the weather display board shows the mild reaction conditions, while the CN Tower outside the baseball field in the background is the landmark of Toronto, where this research was conducted. The blue-white “outfit” of the batter corresponds to the Toronto local team colors. More information can be found in the Research Article by D. Song and co-workers.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.002 | 0.001 |
| Research integrity | 0.000 | 0.002 |
| Insufficient payload (model declined to judge) | 0.007 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".