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Record W4381511376 · doi:10.5267/j.ccl.2023.5.006

Insecticidal thioureas: Preparation and biochemical impacts of some novel thiobenzamide derivatives as potential eco-friendly insecticidal against the cotton leafworm, Spodoptera littoralis (Boisd.)

2023· article· en· W4381511376 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueCurrent Chemistry Letters · 2023
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicFungal Plant Pathogen Control
Canadian institutionsnot available
Fundersnot available
KeywordsSpodoptera littoralisChemistryBenzamideInsect growth regulatorPesticideInstarMode of actionInsectLarvaOrganic chemistryStereochemistryToxicologyNoctuidaeBotanyBiochemistryBiologyAgronomy

Abstract

fetched live from OpenAlex

The following work could bring new insights into the application of heterocyclic N, N′-substituted thiobenzamide derivatives as novel pesticides. Insect growth regulators such as chitin synthesis inhibitors seem promising because of their specific mode of action on insects and their lower toxicity against vertebrates than conventional insecticides. Thus, a novel series of thiobenzamide derivatives have been prepared in a pure state. The structure of these synthesized compounds which related to the most famous insect growth regulator insecticides, were confirmed by elemental and modern spectroscopic analyses (IR, UV, 1HNMR and 13CNMR). Toxicological and biochemical parameters of the synthesized compounds against the cotton leafworm, Spodoptera littoralis under laboratory conditions were also investigated. Regarding the determined LC50 value for compound 2,4-Dichloro-N-[(2-methoxyphenyl)carbamothioyl]- benzamide 14 showed the most potent toxic effects than the other synthetic target compounds, with LC50 46.84 ppm of 2nd instar larvae and LC50 148.05of the 4th instar larvae.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.029
Threshold uncertainty score0.537

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.233
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it