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Record W4381611179 · doi:10.32920/23560920.v1

Comparison of Mercury and Lead Sediment Concentrations in Lake Ontario (1968–1998) and Lake Erie (1971–1997/98) using a GIS-Based Kriging Approach

2023· preprint· en· W4381611179 on OpenAlexaffabout
K. Wayne Forsythe, Michael Dennis, Chris Marvin

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEnvironmental Science
TopicSoil Geostatistics and Mapping
Canadian institutionsEnvironment and Climate Change CanadaToronto Metropolitan University
Fundersnot available
KeywordsKrigingSedimentMercury (programming language)ShoreEnvironmental scienceHydrology (agriculture)ContaminationPhysical geographyGeologyGeographyOceanographyEcologyGeomorphology

Abstract

fetched live from OpenAlex

<p>This research analyzed sediment contamination concentrations for mercury and lead in Lakes Ontario and Erie using a GIS-based kriging approach. Environment Canada provided sediment survey data for Lake Ontario (1968 and 1998) and Lake Erie (1971 and 1997/98). Collation and mapping of point measurement data without the application of interpolation methods does not allow for spatial data trends to be fully analyzed. The kriging technique enables the creation of interpolated prediction surfaces, with the advantage that the results can be statistically validated. Although data normality is not required, the kriging results for the historical datasets suggest that it may be desirable, as statistical validity was reduced due to some individual stations having very high contaminant concentrations. Three of the four models developed for the 1997/98 data were statistically valid. For both lakes, the more recent data reveal reduced concentrations of mercury and lead, and there has been an overall reduction in contamination levels. However, sediments in some areas still exceeded Canadian sediment quality guidelines. The areas of greatest sediment contamination in Lake Ontario were within the major depositional basins, presum- ably as a result of historical industrial activities in watersheds along the southern and western shoreline including the Niagara River. In Lake Erie, areas of greatest sediment contamination continue to be located in the western and south central portions of the lake in proximity to the Detroit River and major urban/industrial centres. </p>

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.821
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.084
GPT teacher head0.313
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2023
Admission routes2
Has abstractyes

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